Matt & Ana are out!
In a surprise ending of the first episode we saw these two compete against and at no time were they last. Until the last leg of the trip where they got in to drive to the final location. Unfortunately they couldn't find the location and took most of the night before they finally showed up. They were the first couple to get eliminated.
Matt and Ana met in 1995, while they were both in the Army. When they drove together from Washington State to New York, "it was a fun trip and [they] acted like rebels." Their combined strengths make them a good Team for THE AMAZING RACE: while Matt is very hyper and energetic, Ana remains calm and efficient.